Correction to: Structural similarity, synthesis, and adsorption properties of aluminum-based metal-organic frameworks

Synthesis and hydrogen adsorption properties of internally polarized 2,6-azulenedicarboxylate based metal–organic frameworks

Chemisches Institut, Universitat Zurich, W Switzerland. E-mail: [email protected]; 6802 Institut für Anorganische Chemie und Struk Düsseldorf, Germany Department of Chemistry, University of Division, Lawrence Berkeley National L Institute at Berkeley, Berkeley, California 947 King Fahd University of Petroleum and Min † Electronic supplementary information synthesis of 2,6-H2azd), Fig. S1–S3 (m...

Metal-organic frameworks: structure, properties, methods of synthesis and characterization

Azulene based metal-organic frameworks for strong adsorption of H2.

Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H(2) interactions (7.8-6.8 kJ mol(-1)), which revealed the significant impact of internally polarized azulene backbone to stabilized H(2) molecules in the framework.

Metal-Organic Frameworks to Metal/Metal Oxide Embedded Carbon Matrix: Synthesis, Characterization and Gas Sorption Properties

Three isostructural metal-organic frameworks, (MOFs), [Fe(OH)(1,4-NDC)] (1), [Al(OH)(1,4-NDC)] (2), and [In(OH)(1,4-NDC)] (3) have been synthesized hydrothermally by using 1,4-naphthalene dicarboxylate (1,4-NDC) as a linker. The MOFs were characterized using various techniques and further used as precursor materials for the synthesis of metal/metal oxide nanoparticles inserted in a carbon matri...

Adsorption Deformation and Structural Transitions in Metal−Organic Frameworks: From the Unit Cell to the Crystal

Much attention has recently been focused on soft porous crystals, a fascinating subclass of metal−organic frameworks that behave in a remarkable stimuliresponsive fashion, presenting structural changes of large amplitude in response to guest adsorption, mechanical pressure, or variations in temperature. In this Perspective, we summarize the recently developed thermodynamic and mechanical theore...